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Beilstein J. Org. Chem. 2015, 11, 1148–1154, doi:10.3762/bjoc.11.129
Graphical Abstract
Figure 1: Compounds 1–3.
Scheme 1: Synthesis of compound 4.
Scheme 2: Synthesis of compounds 1 and 2.
Figure 2: UV–vis absorption spectra of 10−5 M solutions of compounds 1 (black) and 2 (red) in dichloromethane....
Figure 3: Cyclic voltammograms showing the reduction (left) and oxidation (right) of compounds 1 (top) and 2 ...
Figure 4: Optimised structures of 1 (left), 2 (centre) and 3 (right).
Figure 5: Output characteristics of OFETs fabricated using compound 2 in CHCl3 with OTS (top) and PFBT/OTS (b...
Figure 6: AFM images of OFET devices fabricated using compound 2 in CHCl3 with OTS (left) and PFBT/OTS (right...
Beilstein J. Org. Chem. 2013, 9, 1243–1251, doi:10.3762/bjoc.9.141
Figure 1: Labelled truxene and compounds T1 and T4.
Scheme 1: Synthesis of the thiophene-fluorene arm for the 3-isomer.
Scheme 2: Synthesis of the thiophene-fluorene arm for the 4-isomer.
Scheme 3: Coupling of arms to the truxene core.
Scheme 4: Synthesis of T4-4FTh.
Figure 2: Normalised absorbance (solid) and emission (dashed) of materials in solution (dichloromethane).
Figure 3: HOMO−1 (bottom, left), HOMO (bottom, right), LUMO (top, left) and LUMO+1 (top, right) of T1-3FTh.
Figure 4: HOMO−1 (bottom, left), HOMO (bottom, right), LUMO (top, left) and LUMO+1 (top, right) of T1-4FTh.